Fluoroboric acid (also known as tetrafluoroboric acid or hydrofluoboric acid) is a strong inorganic acid composed of the tetrafluoroborate anion ($\text{BF}_4^-$) and a proton ($\text{H}^+$). It exists commercially almost exclusively as an aqueous solution (typically $40-50\%$ concentration) because pure, anhydrous $\text{HBF}_4$ is unstable.
Key Chemical & Physical Properties
| Property |
Specification / Value |
| Chemical Formula |
$\text{HBF}_4$ |
| CAS Registry Number |
16872-11-0 |
| Molar Mass |
$87.81\text{ g/mol}$ |
| Appearance |
Clear, colorless liquid |
| Density |
$\sim1.28 - 1.40\text{ g/cm}^3$ (for $40-50\%$ aqueous solutions) |
| Boiling Point |
$\sim130^\circ\text{C}$ (decomposes) |
| Acidity ($\text{p}K_a$) |
$-4.9$ (Strong acid, fully ionized in water) |
| Solubility |
Fully miscible with water and alcohols |
Key Features & Chemical Behavior
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Non-Coordinating Anion: The tetrafluoroborate anion ($\text{BF}_4^-$) is weakly coordinating, making fluoroboric acid ideal for preparing metal salts with reactive cations or generating free carbonium ions in organic synthesis.
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Etching & Cleansing Capability: Dissolves metal oxides and silica without the extreme volatility and hazards of concentrated hydrofluoric acid ($\text{HF}$).
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Thermal Decomposition: Upon heating, aqueous fluoroboric acid decomposes into water, boron trifluoride gas ($\text{BF}_3$), and hydrofluoric acid ($\text{HF}$).
Primary Applications
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Electroplating & Metal Surface Treatment: Widely used in tin, lead, copper, and alloy electroplating baths to prepare smooth, corrosion-resistant metallic coatings.
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Organic Synthesis & Catalysts: Serves as an acid catalyst in alkylation, polymerization, and esterification reactions, as well as in the synthesis of diazonium tetrafluoroborate salts (used in the Schiemann reaction to prepare aryl fluorides).
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Aluminum & Glass Processing: Used as a flux constituent, oxide-stripping agent, and surface cleaning agent prior to soldering or plating.
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Preparation of Tetrafluoroborate Salts: Primary precursor for synthesizing various fluoroborate salts (such as sodium, potassium, or ammonium tetrafluoroborates).
Safety & Handling
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Corrosive Hazard: Highly corrosive to skin, eyes, and metals (UN 1775, Hazard Class 8).
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Storage Warning: Slowly attacks standard glass over long storage periods due to trace equilibrium $\text{HF}$. It must be stored in specialized plastic containers (HDPE, polypropylene, or fluoropolymers).
Trade & Identification Details