Chromium(III) nitrate is an inorganic chemical compound consisting of chromium in its $+3$ oxidation state paired with nitrate anions. Commercial forms are almost exclusively found as the hydrated salt, Chromium(III) nitrate nonahydrate ($\text{Cr}(\text{NO}_3)_3 \cdot 9\text{H}_2\text{O}$).
Key Chemical & Physical Properties
| Property |
Anhydrous Form |
Nonahydrate Form (Most Common) |
| Chemical Formula |
$\text{Cr}(\text{NO}_3)_3$ |
$\text{Cr}(\text{NO}_3)_3 \cdot 9\text{H}_2\text{O}$ |
| CAS Registry Number |
13520-68-3 |
7789-02-8 |
| Molar Mass |
$238.01\text{ g/mol}$ |
$400.15\text{ g/mol}$ |
| Appearance |
Green-black powder / crystals |
Dark purple-violet to deep blue-green crystals |
| Density |
$1.85\text{ g/cm}^3$ |
$1.80\text{ g/cm}^3$ |
| Melting Point |
Decomposes |
$\sim60^\circ\text{C}$ (dissolves in its own water of crystallization) |
| Thermal Decomposition |
Decomposes $>100^\circ\text{C}$ |
Decomposes to $\text{Cr}_2\text{O}_3$, $\text{NO}_2$, and $\text{O}_2$ around $100^\circ\text{C}$ |
| Solubility in Water |
Soluble |
Highly soluble ($\sim81\text{ g/100 mL}$ at $20^\circ\text{C}$) |
| Solubility in Solvents |
Soluble in alcohol, acetone |
Soluble in ethanol, methanol, and acetone |
| Aqueous Solution pH |
Acidic |
Acidic ($\text{pH } 2 - 3$) |
Structure & Coordination
In its aqueous or hydrated state, chromium(III) nitrate forms the hexaaquachromium(III) complex ion $[\text{Cr}(\text{H}_2\text{O})_6]^{3+}$, surrounded by three nitrate anions ($\text{NO}_3^-$) and three uncoordinated lattice water molecules. This octahedral complex gives aqueous solutions and crystals their characteristic deep reddish-purple or dark green appearance.
Primary Applications
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Catalyst Manufacturing: Serves as a primary precursor for synthesizing chromium-based, alkali-metal-free catalysts used in organic oxidation and polymerization reactions.
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Textile & Leather Processing: Used as a mordant in textile printing and dyeing operations to bind dyes to fibers, as well as in specialized leather tanning.
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Corrosion Control & Metal Finishing: Used as a surface treatment agent and corrosion inhibitor on metal surfaces.
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Chemical Synthesis: Used as a source of soluble $\text{Cr}^{3+}$ ions to synthesize other chromium chemicals, inorganic pigments, and chrome oxide coatings.
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Laboratory Reagent: Applied in analytical chemistry as a reagent and in biochemistry research.
Safety & Handling
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Oxidizing Agent: As a nitrate salt, it is an oxidizer (UN 2720, Hazard Class 5.1). Keep away from combustible materials, organic solvents, and strong reducing agents.
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Irritant: Causes skin and eye irritation; exposure to dust or mists should be avoided. Use suitable personal protective equipment (gloves, safety goggles, and dust mask).
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Toxicity: $\text{Cr(III)}$ compounds are significantly less toxic than carcinogenic hexavalent chromium ($\text{Cr(VI)}$), but standard precautions for heavy metal salt disposal apply.
Trade & Identification Details